Development of a General and Selective Nanostructured Cobalt Catalyst for the Hydrogenation of Benzofurans, Indoles and Benzothiophenes

The selective hydrogenation of benzofurans in the presence a heterogeneous non-noble metal catalyst is reported. developed optimal catalytic material consists cobalt-cobalt oxide core–shell nanoparticles supported on silica, which has been prepared by immobilization and pyrolysis cobalt-DABCO-citric acid complex silica under argon at 800 °C. This novel allows for simple functionalized to 2,3-dihydrobenzofurans as well related heterocycles. versatility reported protocol showcased reduction selected drugs deuteration Further, stability, recycling, reusability Co-nanocatalyst are demonstrated.